间三联苯安全技术说明书
Product Identification
【Product Name】1,3-Diphenylbenzene
【Synonyms】m-Diphenylbenzene
【CAS】92-06-8
【Formula】C18H14
【Molecular Weight】230.32
【EINECS】202-122-1
【RTECS】WZ6470000
【RTECS Class】Other
【Beilstein/Gmelin】1864778
【Beilstein Reference】4-05-00-02480

Physical and Chemical Properties
【Appearance】Yellow needles from alc. Faint, pleasant odor /commercial terphenyl mixtures/.
【Solubility in water】Insoluble
【Melting Point】86-87℃
【Boiling Point】379℃
【Vapor Pressure】0.01 (20℃)
【Density】1.20 g/cm3 (20℃)
【Heat Of Vaporization】64.2 kj/mol
【Usage】Terphenyl mixtures are used industrially as heat storage and transfer agents, as textile dye carriers, and as intermediates in the production of nonspreading lubricants. From 1960-1970, technical grade terphenyls were used as coolants for nuclear reactors, whereas contemporary use has been in solar-heating systems. Terphenyl mixtures.

First Aid Measures
【Ingestion】Dilution: following ingestion and/or prior to gastric evacuation, immediately dilute with 4 to 8 ounces (120 to 240 ml) of milk or water (not to exceed 15 ml/kg in a child). Consider after ingestion of a potentially life-threatening amount of poison if it can be performed soon after ingestion (generally within 1 hour). Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.
【Inhalation】Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 anist and corticosteroid aerosols.
【Skin】Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
【Eyes】Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Handling and Storage
【Storage】Keep tightly closed. Store in a cool and dry place.
【Handling】All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification
【Inhalation】Respiratory tract irritation and bronchitis have been reported.
【Skin】Percutaneous absorption through intact skin has been noted.
【Eyes】Eye and mucous membrane irritation may occur.
【Ingestion】Nausea, diffuse pain, and indigestion have been reported in workers with prolonged exposure to biphenyl.
【Hazards】Fire may produce irritating or poisonous gases.
【EC Risk Phrase】R 36/37/38
【EC Safety Phrase】S 26 36
【UN (DOT)】1325

Exposure Controls/Personal Protection
【Personal Protection】Wear appropriate protective gloves, clothing and ggles.
【Respirators】Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
【Exposure Effects】Headache, fatigue, numbness, and aching limbs have occurred in workers. Peripheral and central nerve damage may occur.
【Exposure limit(s)】NIOSH REL: C 5 mg/m3 (0.5 ppm) OSHA PEL: C 9 mg/m3 (1 ppm) IDLH 500 mg/m3
【Poison Class】4

Fire Fighting Measures
【Flash Point】191℃
【Fire Fighting】Carbon dioxide, dry chemical.
【Upper exp. limit】3.4
【Lower exp. limit】.5
【Fire Potential】Slight fire risk when exposed to heat or flame.

Accidental Release Measures
【Small spills/leaks】Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

Stability and Reactivity
【Incompatibilities】Incompatible with oxidizing agents.
【Stability】Stable.
【Decomposition】Oxides of carbon.
【Combustion Products】Fire may produce irritating and/or toxic gases.

Transport Information
【UN Number】1325
【Hazard Class】4.1
【Packing Group】II; III