Product Identification
【Product Name】4-Morpholinecarboxaldehyde；N-甲酰吗啉
【Synonyms】4-Formylmorpholine
【CAS】4394-85-8
【Formula】C5H9NO2
【Molecular Weight】115.13
【EINECS】224-518-3
【RTECS】QD9694000
【RTECS Class】Primary Irritant
【Beilstein/Gmelin】110293
【Beilstein Reference】4-27-00-00274

Physical and Chemical Properties
【Appearance】White solid.
【Solubility in water】Very soluble
【Melting Point】23℃
【Boiling Point】240℃
【Vapor Pressure】7.5 (20℃)
【Density】0.881 g/cm3 (20℃)
【Heat Of Vaporization】72.85 kJ/mol
【Refractive Index】1.4855 (18℃)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification
【Ingestion】Ingestion of large amounts may cause gastrointestinal irritation.
【Inhalation】May cause respiratory tract irritation.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation.
【EC Safety Phrase】S 24/25

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】118℃
【Autoignition】345℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Upper exp. limit】8.2
【Lower exp. limit】1.2

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity
【Disposal Code】3
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information
【HS Code】2934 99 90