Product Identification
【Product Name】alpha,2,6-Trichlorotoluene
【Synonyms】2,6-二氯氯苄
【CAS】2014-83-7
【Formula】C7H5Cl3
【Molecular Weight】195.47
【EINECS】217-940-4
【Beilstein/Gmelin】4230721
【Beilstein Reference】5-21-07-00211

Physical and Chemical Properties
【Appearance】White solid.
【Solubility in water】Insoluble
【Melting Point】49~50℃
【Boiling Point】248℃
【Vapor Pressure】0.04 (25℃)
【Partition Coefficient】2.69
【Heat Of Vaporization】46.6 kJ/mol

First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
【Handling】Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.

Hazards Identification
【Ingestion】The toxicological properties of this substance have not been fully investigated.
【Inhalation】The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation.
【Skin】May cause severe skin irritation and burns.
【Eyes】Contact with eyes may cause severe irritation, and possible eye burns.
【Hazards】Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】R 34 36/37
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】3261

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】158℃
【Autoignition】>450℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Do not get water inside containers.

Stability and Reactivity
【Incompatibilities】Bases, amines, oxidizing agents, alcohols. Corrodes steel.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Hydrogen chloride, carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】3261
【Hazard Class】8
【Packing Group】I; II; III