Product Identification
【Product Name】1,2-Dimethylimidazole
【Synonyms】N,2-Dimethylimidazole ;1,2-二甲基咪唑
【CAS】1739-84-0
【Formula】C5H8N2
【Molecular Weight】96.13
【EINECS】217-101-2
【RTECS】NI4838854
【RTECS Class】Other
【Beilstein/Gmelin】4155088
【Beilstein Reference】1-14-00-00592
【EC Index Number】613-034-00-1
【EC Class】Harmful; Irritant
Physical and Chemical Properties
【Appearance】Yellow chunks.
【Solubility in water】Very soluble
【Melting Point】38℃
【Boiling Point】204℃
【Vapor Pressure】0.35 (25℃)
【Density】1.084 g/cm3 (20℃)
【pKa/pKb】6.24 (pKb)
【Partition Coefficient】-.13
【Heat Of Vaporization】42.4 kJ/mol
【Usage】Vulcanizing agent.
【Refractive Index】1.4945 (25℃)
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and Storage
【Storage】Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Handling】Minimize dust generation and accumulation. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Hazards Identification
【Ingestion】May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【Inhalation】May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
【Skin】Causes skin burns.
【Eyes】Causes eye burns.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 22 38 41
【EC Safety Phrase】S 24 26
【UN (DOT)】3263
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】4
Fire Fighting Measure
【Flash Point】73℃
【Autoignition】480℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.
Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Disposal Code】1
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】3263
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2933 29 90