Product Identification
【Product Name】4-Chlorobutyronitrile
【Synonyms】g-Chlorobutyronitrile
【CAS】628-20-6
【Formula】C4H6ClN
【Molecular Weight】103.55
【EINECS】211-031-6
【RTECS】ET9020000
【RTECS Class】Other
【Beilstein/Gmelin】1633582
【Beilstein Reference】4-02-00-00827

Physical and Chemical Properties
【Appearance】Clear, colorless liquid.
【Solubility in water】Soluble
【Melting Point】-44 ℃
【Boiling Point】196 ℃
【Density】1.162 g/cm3 (10℃)
【Partition Coefficient】1.27
【Vapor Density】3.57
【Refractive Index】1.4421 (15℃)
 
First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.

Hazards Identification
【Inhalation】Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
【Skin】Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities.
【Eyes】Causes eye irritation. May cause chemical conjunctivitis and corneal damage.
【Ingestion】Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 23/24/25 36/38
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2810

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Effects may be delayed.

Fire Fighting Measures
【Flash Point】91
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Stability and Reactivity
【Disposal Code】2
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong acids, strong bases, strong oxidizing agents, strong reducing agents.
【Decomposition】Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】Toxic and irritating hydrogen cyanide, hydrogen bromide, and hydrogen chloride may form in fires.

Transport Information
【UN Number】2810
【Hazard Class】6.1
【Packing Group】I; II; III
【HS Code】2926 90 95