Product Identification
【Product Name】Methyl 4-iodobenzoate 对碘苯甲酸甲酯
【Synonyms】4-Iodobenzoic acid methyl ester
【CAS】619-44-3
【Formula】C8H7IO2
【Molecular Weight】262.04000000000002
【EINECS】210-597-1
【Beilstein/Gmelin】2208132
【Beilstein Reference】4-09-00-01036

Physical and Chemical Properties
【Appearance】Solid.
【Solubility in water】Insoluble
【Melting Point】112℃
【Boiling Point】276℃
【Vapor Pressure】0.005 (25℃)
【Density】2.02 g/cm3 (10℃)
【Partition Coefficient】3.4
【Heat Of Vaporization】51.5 kJ/mol
【Heat Of Combustion】-3866 kJ/mol
【Vapor Density】9.03

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Store in a cool, dry place. Keep container closed when not in use.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification
【Ingestion】The toxicological properties of this substance have not been fully investigated. Causes gastrointestinal tract irritation.
【Inhalation】Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】Causes skin irritation. The toxicological properties of this material have not been fully investigated.
【Eyes】Causes eye irritation. The toxicological properties of this material have not been fully investigated.

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures
【Flash Point】121
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity
【Incompatibilities】Oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate).
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, iodine.