Product Identification
【Product Name】1-Bromo-2,4-difluorobenzene
【Synonyms】2,4-Difluorophenyl bromide；2,4-二氟溴苯
【CAS】348-57-2
【Formula】C6H3BrF2
【Molecular Weight】192.99
【EINECS】206-479-4
【Beilstein/Gmelin】1680892
【Beilstein Reference】4-05-00-00679
【EC Class】flammable, irritant

Physical and Chemical Properties
【Appearance】Clear very slight yellow liquid.
【Solubility in water】Insoluble
【Melting Point】-4℃
【Boiling Point】145℃
【Density】1.69 g/cm3
【Refractive Index】1.50 (20℃)

First Aid Measures
【Ingestion】Get medical aid. Wash mouth out with water.
【Inhalation】Remove from exposure to fresh air immediately. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.
【Handling】Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification
【Ingestion】The toxicological properties of this substance have not been fully investigated.
【Inhalation】Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will
sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 10 36/37/38
【EC Safety Phrase】S 26 36
【UN (DOT)】1993

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】51℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.

Stability and Reactivity
【Disposal Code】3
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Carbon monoxide, carbon dioxide, hydrogen fluoride, hydrogen bromide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】1993
【Hazard Class】3
【Packing Group】I; II; III
【HS Code】2903 69 90