锂盐阴离子和不同侧基的15-冠-5系冠醚对锂盐/冠醚固态配合物远红外位移的影响

温永红； 杨恩波； 傅立安； 方胜强；

兰州大学化学化工学院； 中国原子能科学研究院； 兰州大学化学化工学院 兰州730000； 北京102413； 兰州730000；

摘要 Two reduced sequences of(s/s′)f (relative reduced partition function ratio) found in the present paper are LiSCN·B15C5>LiCCl3COO·B15C5 > LiClO4·B15C5 and LiClO4·4-mB15C5>LiClO4·B15C5>LiClO4·Ph15C5,respectively.These solid lithium complexes with crown ethers were separated from tetrahydrofuran for the first sequence and from 3-methyl-1-butanol for the second one,respectively.Acording to the analysis of the data obtained,an independent character of the three factors(solvents,anion of lithium salts,and the sidegroup of 15C5 series),playing a part in contribution to(s/s′)f,have been brought to light preliminarily.

关键词 锂盐/冠醚的固态配合物； 远红外位移； 锂同位素； 相对约化配分函数比(s/s′)f；

论文　稀土冠醚配合物的研究XX_Schiff碱型_省略_苯并15-冠-5稀土配合物.caj