1,8-二羟基蒽醌安全技术说明书
Product Identification
【Product Name】1,8-Dihydroxyanthraquinone
【Synonyms】Danthron
【CAS】117-10-2
【Formula】C14H8O4
【Molecular Weight】240.22
【EINECS】204-173-5
【RTECS】CB6650000
【RTECS Class】Tumorigen; Drug; Mutagen; Primary Irritant
【Merck】13,2841
【Beilstein/Gmelin】2054727
【Beilstein Reference】4-08-00-03271

Physical and Chemical Properties
【Appearance】Orange crystalline powder. Almost odorless and tasteless.
【Solubility in water】Insoluble
【Melting Point】190 - 193℃
【Boiling Point】sublimes
【Density】1.537 g/cm3
【Usage】Intermediate in the production of alizarin and indanthrene dyestuffs.
【Vapor Density】8.3
【Refractive Index】1.787 (20℃)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification
【Inhalation】May cause respiratory tract irritation.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation.
【Ingestion】May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 45
【EC Safety Phrase】S 53 45
【UN (DOT)】2321

Exposure Controls/Personal Protection
【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】May cause cancer in humans.
【Exposure limit(s)】OSHA: Possible Select carcinogen
【Poison Class】3

Fire Fighting Measures
【Flash Point】>200℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.
【Fire Potential】This material is probably combustible.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity
【Disposal Code】3
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents, bases, acid anhydrides, acid chlorides.
【Decomposition】Carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2321
【Hazard Class】6.1
【Packing Group】III
【HS Code】2914 69 90