Product Identification
【Product Name】Malonamide；丙二酰胺
【Synonyms】Malonic diamide
【CAS】108-13-4
【Formula】C3H6N2O2
【Molecular Weight】102.09
【EINECS】203-553-8
【RTECS】ON9125000
【RTECS Class】Other
【Beilstein/Gmelin】1751401
【Beilstein Reference】4-02-00-01887

Physical and Chemical Properties
【Appearance】White powder.
【Solubility in water】Very soluble
【Melting Point】169-170℃
【Boiling Point】461℃
【Vapor Pressure】1E-8 (25℃)
【Density】1.43 g/cm3
【pKa/pKb】7.00 (pKa)
【Partition Coefficient】-2.55
【Heat Of Vaporization】72.2 kJ/mol
【Heat Of Combustion】-1495 kJ/mol

First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Store in a cool, dry place. Store in a tightly closed container.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe dust.

Hazards Identification
【Ingestion】The toxicological properties of this substance have not been fully investigated.
【Inhalation】The toxicological properties of this substance have not been fully investigated.
【Skin】May cause skin irritation.
【Eyes】May cause eye irritation.
【EC Safety Phrase】S 22 24/25

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures
【Flash Point】233℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Stability and Reactivity
【Disposal Code】3
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents, strong reducing agents, acids, bases.
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide.

Transport Information
【HS Code】2924 19 00