Product Identification
【Product Name】4'-Methoxyacetophenone
【Synonyms】Linarodin
【CAS】100-06-1
【Formula】C9H10O2
【Molecular Weight】150.18
【EINECS】202-815-9
【RTECS】AM9240000
【RTECS Class】Human Data; Primary Irritant
【Beilstein/Gmelin】742313
【Beilstein Reference】4-08-00-00340
【EC Class】harmful

Physical and Chemical Properties
【Appearance】White to pale yellow solid. Pleasant odor.
【Solubility in water】Slightly soluble
【Melting Point】36 - 38
【Boiling Point】152
【Vapor Pressure】0.0005 (3 C)
【Density】1.14 g/cm3 (20 C)
【Refractive Index】1.547 (41 C)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
【Skin】Get medical aid if irritation develops or persists. Wash clothing before reuse. Flush skin with plenty of soap and water.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards Identification
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
【Inhalation】May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Human systemic effects by inhalation include: a pulse rate increase without a fall in blood pressure and blood pressure elevation.
【Skin】May cause skin irritation.
【Eyes】May cause eye irritation.
【EC Risk Phrase】R 22 36/38
【EC Safety Phrase】S 26 36

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】138
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.

Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Disposal Code】3
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions. May discolor on exposure to light.
【Incompatibilities】Strong oxidizng agents, strong bases.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Transport Information
【HS Code】2914 50 00